Collaborative Research Center 1333
Molecular Heterogeneous Catalysis in Confined Geometries
Poly(urethane)-based polymeric monolithic materials with mesopores, e.g., 5, 10, 15 or 20±1 nm in diameter, will be generated. Janus-type nanoparticles equipped with one polymer-compatible and one polymer-incompatible hemisphere will be used in course of monolith synthesis such that they are finally located and half-embedded at the surface of the structure forming microglobules. Alternatively, polymeric monoliths with a defined pore-size distribution will be generated via solvent-induced phase separation. Pore-size selective functionalization approaches are outlined.
H. Acikalin, P. K. R. Panyam, A. W. Shaikh, D. Wang, S. R. Kousik, P. Atanasova and M. R. Buchmeiser Macromol. Chem. Phys. 2023, 224, 2200234.
J. Groos, M. Koy, J. V. Musso, M. Neuwirt, T. Pham, P. M. Hauser, W. Frey, and M. R. Buchmeiser Organometallics 2022, 41, 10, 1167–1183.
P. K. R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer and M. R. Buchmeiser Chem. Eur. J. 2021, 27, 17220–1722.
H. Acikalin, F. Ziegler, D. Wang and M. R. Buchmeiser Macromol. Chem. Phys. 2021, 222, 2100247.
J. De Jesus Silva, D. Mance, M. Pucino, M. J. Benedikter, I. Elser, M. R. Buchmeiser and Ch. Copéret Helv. Chim. Acta 2020, 103, e2000161.
C. Rieg, D. Dittmann, Z. Li, A. Kurtz, I. Lorenz, D. P. Estes, M. R. Buchmeiser, M. Dyballa and M. Hunger Microporous Mesoporous Mater. 2020, 310, 110594.
P. K. R. Panyam, L. Stöhr, D. Wang, W. Frey and M. R. Buchmeiser Eur. J. Inorg. Chem. 2020, 3673-3681.
M. Pucino, W.‐C. Liao, K. W. Chan, E. Lam, R. Schowner, P. A. Zhizhko, M. R. Buchmeiser and C. Copéret Helv. Chim. Acta 2020, 103, e2000072.
R. Schowner, I. Elser, M. J. Benedikter, M. Momin, W. Frey, T. Schneck, L. Stöhr and M. R. Buchmeiser Angew. Chem. Int. Ed. 2020, 59, 951-958.
F. Ziegler, J. Teske, I. Elser, M. Dyballa, W. Frey, H. Kraus, N. Hansen, J. Rybka, U. Tallarek and M.R. Buchmeiser J. Am. Chem. Soc. 2019, 141, 19014-19022.
M. Dyballa, C. Rieg, D. Dittmann, Z. Li, M. R. Buchmeiser, B. Plietker and M. Hunger Microporous Mesoporous Mater. 2020, 293, 109778.
M. Pucino, M. Inoue, C. P. Gordon, R. Schowner, L. Stöhr, S. Sen, C. Hegedüs, E. Robé, F. Tóth, M. R. Buchmeiser and C. Copéret Angew. Chem. Int. Ed. 2018, 57, 4566–14569
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